LOW‑LEVEL CATIONISATION OF CELLULOSE

The conventional dyeing of cellulose fibres including cotton as its most prominent representative consumes large amounts of inorganic electrolytes and fresh water, resulting in high salinity and coloured wastewater. These effluents can cause serious environmental pollution and pose a potential threat to living organisms. In order to make reactive dyeing more sustainable, different approaches are pursued, including the cationization of cellulose fibres. The use of cationic fibres allows salt free dyeing and thus helps to reduce wastewater.

Cationisation of cellulose fibres has been studied extensively as an alternative to permit salt free reactive dyeing, however chemical balances of the cationisation reaction often are not taken into account. The chemical consumption of cationization processes described in the literature is substantial and often over-compensates savings in salt in a conventional reactive dyeing. Besides very high consumption of chemicals the high level of cationization generates problems of uneven dyeings and shade variations.

In a new approach low concentrations of 3-chloro-2-hydroxypropyl-N,N,N-trimethylammonium chloride (CHPTAC) were applied in a pad batch cationisation process for cotton fabric to achieve a low level cationisation. The cationic group content of the processed fibres ranged from 5 to 79 mmol kg−1. Exhaust dyeing experiments with Reactive Blue 19 demonstrated that a salt free reactive dyeing is possible with low cationic group content 14 mmol kg−1.

The optimised low-level cationisation reduces the overall chemical consumption of the reactive dyeing, and thus represents a cleaner alternative to present reactive dyeing operations which are based on addition of high amounts of salt.

Publication:

Setthayanond, F. Netzer, K. Seemork, P. Suwanruji,
T. Bechtold, T. Pham, A.P. Manian, Low‑level cationisation of cotton opens a chemical saving route to salt free reactive dyeing, Cellulose. (2023).
https://doi.org/10.1007/s10570-023-05136-5